The win increased Zinedine Zidane's side's advantage at the top of the standings to six points
The win took second-placed Real to 62 points after 29 games, two behind champions Barca who beat Leganes 2-0 on Tuesday.
The Portuguese forward put his team on the verge of their third final in four years and took his tally to 103 goals in the competition as he helped Madrid vanquish their neighbours at the Santiago Bernabeu.
Real Madrid defender Nacho was the unlikely hero as they snatched a 1-0 win at Real Valladolid on Sunday to capitalise on Barcelona's defeat at Valencia this weekend and move three points clear of their rivals at the top of La Liga. Serie A leaders Juventus suffered a shock 2-1 defeat at Napoli on Sunday, with coach Maurizio Sarri returning to his former club for the first time, though Cristiano Ronaldo still managed to score for an eighth league game in a row for the visitors.
Real Madrid forwards Marco Asensio and Karim Benzema struck to give their side a 2-0 win at home to Eibar in La Liga
Barcelona coach Ronald Koeman has joined other managers in lashing out at the packed European football calendar after deciding to rest Lionel Messi for Tuesday's Champions League trip to Dynamo Kyiv.
News of all that's transpired on and off the football field
Barcelona's last Champions League triumph came in 2015, and since then they have failed to get beyond the quarter-finals while Real Madrid have monopolised the trophy.
News of all that's transpired on and off the football field
Real Madrid's Sergio Ramos scored in the 90th minute to hold FC Barcelona to a 1-1 draw at the Camp Nou on Saturday.
Alvaro Morata again proved decisive from the bench by striking a late winner against Athletic Bilbao and firing a lacklustre Real Madrid to the top of La Liga on Sunday. The Spain international has been afforded limited opportunities in his first season back at Real following two years with Juventus, struggling to usurp first choice forwards Gareth Bale, Cristiano Ronaldo and Karim Benzema. Morata has made just four league starts, but has scored four times in all competitions.
Cristiano Ronaldo may have played his last game for Real Madrid after winning a fourth Champions League crown with the Spanish side in a 3-1 victory over Liverpool on Saturday, saying he would soon make an announcement on his future.
Facts and figures ahead of Saturday's Champions League final between holders Real Madrid and Liverpool in Kiev:
Holders Real Madrid reached the Champions League final for a third year in a row after taking advantage of Bayern Munich's carelessness in attack and defence to draw 2-2 in their semi-final second leg on Tuesday, and winning 4-3 on aggregate, at the Santiago Bernabeu, in Madrid, Spain, on Tuesday.
Holders Real Madrid came from a goal down to snatch a precious 2-1 victory at wasteful Bayern Munich on Wednesday and carry a considerable advantage into their Champions League semi-final second leg in Spain.
A game isn't over until the final whistle blows, says Pratik Gour, co-founder of Footprynt, an influencer marketing agency.
Here is a look at what happened in their previous Euro semis...
Like an ailing heavyweight, Spain and their hopes of a third straight European title ended in a tame surrender as their 2-0 defeat by Italy represented the definitive end to a golden era in their footballing history. A first-half effort from defender Giorgio Chiellini and a stoppage-time goal by striker Graziano Pelle sent the Azzurri into the quarter-finals at Euro 2016 and left Spain to mull over a second successive failure on the international stage.
A superb strike from Jose Luis Morales condemned Real Madrid to a 1-0 defeat away to Levante on Saturday which saw them unseated at the top of the La Liga standings by Barcelona. Real's problems deepened with a suspected ankle injury to Eden Hazard, who limped off the pitch four days before their Champions League showdown with Manchester City and a week before their showdown with Barca in the 'Clasico'. Real's problems deepened with a suspected ankle injury to Eden Hazard, who limped off the pitch four days before their Champions League showdown with Manchester City and a week before their showdown with Barca in the 'Clasico'.
Real Madrid are determined to create an intimidating atmosphere for visitors VfL Wolfsburg as they try to overturn a two-goal deficit in Tuesday's Champions League quarter-final second leg at the Santiago Bernabeu stadium.
'They aren't machines, they are the best players in their position but they aren't unbeatable or unsurpassable.'
Barca finished the season second in the standings on 82 points, four behind champions Real Madrid who visit Leganes later on Sunday. Alaves are 16th on 39.
Real Madrid clinched a record-extending 34th La Liga title with one game to spare by beating Villarreal 2-1 at home on Thursday thanks to two goals from their leading scorer Karim Benzema. Real have 86 points after 37 games, seven more than deposed champions Barcelona who were beaten 2-1 at home to Osasuna.
Wolfsburg shock Real Madrid 2-0 to crown big European night.
News of all that's transpired on and off the football field
Italy's top-flight Serie A soccer league launched a new anti-racism campaign on Monday by presenting artwork featuring three side-by-side paintings of apes but the move has been described by campaign group Fare as a sick joke. News of all that's transpired on and off the football field.
Real Madrid and Atletico each slipped 10 points behind La Liga leaders Barcelona after an intense Madrid derby finished goalless and the Catalans picked up an 11th victory in 12 games by winning 3-0 at Leganes.
The injury list in the La Liga keeps growing as the season progresses and this time Lionel Messi and Gareth Bale are the unfortunate victims...
A Marco Asensio-inspired Real Madrid crushed Eibar 3-0 to close the gap on La Liga leaders Barcelona to five points on Sunday, with Karim Benzema starting on the bench.
Playing without crowd will be peculiar: Suarez
Striker Mariano's header was glanced onto the crossbar by Sociedad's Andoni Gorosabel while the loose ball fell to Marco Asensio, whose shot was deflected wide for a corner from which Raphael Varane header hit the top of the bar.
Barcelona forward Ousmane Dembele scored twice and produced a mesmerising display to fire his side to a 5-1 win over Villarreal on Wednesday which stretched the champions' unbeaten run this season to 36 games with two remaining.
Barcelona came through a testing local derby at Espanyol, winning 3-0 to cling to their slender lead at the top of La Liga after rivals Real Madrid had set the challenge by beating Valencia 2-1 in the earlier kick-off.
Cristiano Ronaldo scored a hat-trick to send Real Madrid through to the Champions League semi-finals with a 4-2 extra-time win and 6-3 aggregate success against 10-man Bayern Munich in controversial circumstances on Tuesday.
Real Madrid beat Leganes 4-2 on Wednesday despite resting key players including Cristiano Ronaldo and Gareth Bale as goals from Alvaro Morata and James Rodriguez helped them stay top of La Liga after Barcelona cruised to a 3-0 win over Sevilla.
Atletico Madrid won the La Liga title for the first time since 2014
Cristiano Ronaldo and Gareth Bale both scored as Real Madrid staged a remarkable late comeback from two goals down to win 3-2 at Villarreal and stay top of La Liga.
France head into their World Cup opener against Australia in Kazan on Saturday sweating on the fitness of fullback Djibril Sidibe and under pressure to deliver an emphatic win to erase doubts about the cohesion of a team of brilliant individuals.
Set to start his stint as manager-cum-player of Chennaiyin FC, Italian World Cup winner Marco Materazzi promised to do his best to raise the profile of the game in the country through the Indian Super League which kicks off next month.
Real Madrid's French duo Karim Benzema and Ferland Mendy struck in the second half as the Spanish champions overcame an injury crisis to beat Getafe 2-0 at home on Tuesday and close the gap to La Liga leaders Atletico Madrid to five points.